ASU Electronic Theses and Dissertations
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This investigation is divided into two portions linked together by the momentous reaches of electrochemistry science, principles influencing everyday phenomena as well as innovative research in the field of energy transformation. The first portion explores the strategies for flue gas carbon dioxide capture and release using electrochemical means. The main focus is in the role thiolates play as reversible strong nucleophiles with the ability to capture CO2 and form thiocarbonates. Carbon dioxide in this form is transported and separated from thiocarbonate through electrochemical oxidation to complete the release portion of this catch-and-release approach. Two testing design systems play a fundamental …
- Castro De la Torre, Helme Atic, Friesen, Cody, Buttry, Daniel, et al.
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