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Bioinspired Electrocatalytic Hydrogen Production: Synthetic and Biological Approaches


Abstract Development of efficient and renewable electrocatalytic systems is foundational to creation of effective means to produce solar fuels. Many redox enzymes are functional electrocatalysts when immobilized on an electrode, but long-term stability of isolated proteins limits use in applications. Thus there is interest in developing bio-inspired functional catalysts or electrocatalytic systems based on living organisms. This dissertation describes efforts to create both synthetic and biological electrochemical systems for electrocatalytic hydrogen production.

The first part of this dissertation describes the preparation of three different types of proton reduction catalysts. First, four bioinspired diiron complexes of the form (μ-SRS)Fe(CO)3[Fe... (more)
Created Date 2017
Contributor Laureanti, Joseph Anthony (Author) / Jones, Anne K. (Advisor) / Moore, Thomas (Committee member) / Redding, Kevin E. (Committee member) / Arizona State University (Publisher)
Subject Biochemistry / Bio-inspired / Biomimicry / Catalysis / Electrochemistry / Hydrogenase / Photochemistry
Type Doctoral Dissertation
Extent 286 pages
Language English
Copyright
Reuse Permissions All Rights Reserved
Note Doctoral Dissertation Biochemistry 2017
Collaborating Institutions Graduate College / ASU Library
Additional Formats MODS / OAI Dublin Core / RIS


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Description Dissertation/Thesis