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Synthesis and Characterization of 2D and 3D Metal Organic Frameworks


Abstract Among the alternative processes for the traditional distillation, adsorption and membrane separations are the two most promising candidates and metal-organic frameworks (MOFs) are the new material candidate as adsorbent or membrane due to their high surface area, various pore sizes, and highly tunable framework functionality. This dissertation presents an investigation of the formation process of MOF membrane, framework defects, and two-dimensional (2D) MOFs, aiming to explore the answers for three critical questions: (1) how to obtain a continuous MOF membrane, (2) how defects form in MOF framework, and (3) how to obtain isolated 2D MOFs. To solve the first problem, the accumulated protons in the MOF synthesis solution is proposed to be th... (more)
Created Date 2019
Contributor Shan, Bohan (Author) / Mu, Bin (Advisor) / Forzani, Erica (Committee member) / Dai, Lenore (Committee member) / Lin, Jerry (Committee member) / Liu, Jingyue (Committee member) / Arizona State University (Publisher)
Subject Chemical engineering / Materials Science / Nanotechnology / 2D Materials / Crystal Synthesis / Metal-Organic Frameworks
Type Doctoral Dissertation
Extent 134 pages
Language English
Copyright
Note Doctoral Dissertation Chemical Engineering 2019
Collaborating Institutions Graduate College / ASU Library
Additional Formats MODS / OAI Dublin Core / RIS


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Description Dissertation/Thesis