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Synthesis of Amine-Modified Aerogel Sorbents and Metal-Organic Framework-5 (MOF-5) Membranes for Carbon Dioxide Separation


Abstract Amine-modified solid sorbents and membrane separation are promising technologies for separation and capture of carbon dioxide (CO2) from combustion flue gas. Amine absorption processes are mature, but still have room for improvement. This work focused on the synthesis of amine-modified aerogels and metal-organic framework-5 (MOF-5) membranes for CO2 separation. A series of solid sorbents were synthesized by functionalizing amines on the surface of silica aerogels. This was done by three coating methods: physical adsorption, magnetically assisted impact coating (MAIC) and atomic layer deposition (ALD). CO2 adsorption capacity of the sorbents was measured at room temperature in a Cahn microbalance. The sorbents synthesized by physical adsorpt... (more)
Created Date 2010
Contributor Rosa, Teresa M. (Author) / Lin, Jerry (Advisor) / Pfeffer, Robert (Advisor) / Dai, Lenore (Committee member) / Nielsen, David (Committee member) / Arizona State University (Publisher)
Subject Chemical Engineering / aerogels / amine-modified sorbent / CO<sub>2</sub> separation / gas fluidization / membranes / metal-organic framework 5 (MOF-5)
Type Masters Thesis
Extent 97 pages
Language English
Copyright
Reuse Permissions All Rights Reserved
Note M.S. Chemical Engineering 2010
Collaborating Institutions Graduate College / ASU Library
Additional Formats MODS / OAI Dublin Core / RIS


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Description Dissertation/Thesis